Catalytic Enantioselective Reaction of 2H-Azirines with Thiols Using Cinchona Alkaloid Sulfonamide Catalysts.
| Author | |
|---|---|
| Abstract | :
The first catalytic enantioselective reaction of 2H-azirines with thiols has been developed. The obtained aziridines can be converted to optically active oxazolines, aziridylamides, or α-sulfonyl esters. Transformation of these optically active aziridines showed that 2H-azirines act as β,β-dicarbocationic amine synthons. |
| Year of Publication | :
2018
|
| Journal | :
Organic letters
|
| Date Published | :
2018
|
| ISSN Number | :
1523-7060
|
| URL | :
https://dx.doi.org/10.1021/acs.orglett.7b04022
|
| DOI | :
10.1021/acs.orglett.7b04022
|
| Short Title | :
Org Lett
|
| Download citation |