Geminate and nongeminate recombination of triplet excitons formed by singlet fission.
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| Abstract | :  We report the simultaneous observation of geminate and nongeminate triplet-triplet annihilation in a solution-processable small molecule TIPS-tetracene undergoing singlet exciton fission. Using optically detected magnetic resonance, we identify recombination of triplet pairs directly following singlet fission, as well as recombination of triplet excitons undergoing bimolecular triplet-triplet annihilation. We show that the two processes give rise to distinct magnetic resonance spectra, and estimate the interaction between geminate triplet excitons to be 60 neV. | 
| Year of Publication | :  2014 | 
| Journal | :  Physical review letters | 
| Volume | :  112 | 
| Issue | :  23 | 
| Number of Pages | :  238701 | 
| Date Published | :  2014 | 
| ISSN Number | :  0031-9007 | 
| URL | :  https://link.aps.org/abstract/PRL/v112/p238701 | 
| DOI | :  10.1103/PhysRevLett.112.238701 | 
| Short Title | :  Phys Rev Lett | 
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